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Selective hydrogenation of o-chloronitrobenzene over tin dioxide supported platinum-ruthenium bimetallic nanocatalysts without solvent

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  • Key Words:Chloroaniline; Selective hydrogenation; Solvent-free; Pt-Ru/SnO2; Nano particle

  • Abstract:Colloidal platinum-ruthenium bimetallic nanoparticles with 2.3 nm were synthesized in solution and then immobilized on tin dioxide powder to make a supported nanocatalyst (Pt-Ru/SnO2). The immobilized bimetallic nanoparticles had the same size and size distribution as the solution dispersed ones. Selective hydrogenation of o-chloronitrobenzene to o-chloroaniline was performed over the as-prepared Pt-Ru/SnO2 nanocatalyst without using any solvent; 99.5% selectivity to o-chloroaniline at 100% conversion was achieved. (C) 2013 Elsevier B.V. All rights reserved.

  • Volume:232

  • Issue:232(卷)

  • Translation or Not:no


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