滤筒除尘器不同进风方式对内部流场的影响

Release time:2024-01-19 Hits:

Key Words:MAGNESIUM STORAGE; ELECTROLYTE; INSIGHTS

Abstract:Rechargeable Mg batteries potentially display lower cost and competitive energy density compared with their Li-ion counterparts. However, the practical implementation of high area-capacity cathodes still remains a formidably challenging task. This work presents the sulfur/copper integrated cathodes fabricated by the conventional blade-coating process and slurry-dipping method. The sulfur/copper foil integrated cathodes deliver a high area-capacity of 2.6 mAh cm-2 after 40 cycles, while the sulfur/copperfoam integrated cathode exhibits an ultrahigh area-capacity of 35.4 mAh cm-2, corresponding to 743.1 Wh L-1 at the electrode level (1.5 times higher than the LiCoO2-graphite system). The in-situ formed copper sulfide intermediates with sufficient cation defects can act as functional intermediates to regulate the sulfur electrochemistry during the first discharge process. The subsequent cycles are operated by the reversible displacement reaction between Mg-ions and copper sulfide active substances. In particular, the copper ions prefer to extrude along the [001] direction in copper sulfides lattice and simultaneously the rock-salt MgS crystals are generated. Besides, the nonuniform surface topography of the cycled Mgmetal anode, caused by the spatial inhomogeneity in current distribution, is demonstrated to lead to the battery performance degradation for high area-capacity Mg batteries.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press.

Volume:72

Issue:wu

Translation or Not:no