青岛科技大学  English 
张方坤
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硕士生导师  

教师拼音名称:zhangfangkun

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入职时间:2019-09-02

学历:博士研究生

性别:男

联系方式:18554911864

学位:工学博士

毕业院校:大连理工大学

学科:

化学工程

控制理论与控制工程

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Isobaric vapor-liquid equilibrium of a ternary system of ethyl acetate?+?propyl acetate?+?dimethyl sulfoxide and binary systems of ethyl acetate?+?dimethyl sulfoxide and propyl acetate?+?dimethyl sulfoxide at 101.3?kPa

关键字:Dimethyl sulfoxide;Binary mixtures - Liquids - Phase equilibria - Ternary systems

摘要:Isobaric vapor-liquid equilibrium data were measured for three systems, namely, ethyl acetate + dimethyl sulfoxide, propyl acetate + dimethyl sulfoxide and ethyl acetate + propyl acetate + dimethyl sulfoxide at 101.3 kPa in this work. The experimental data were checked by the Van Ness (point-to-point test) and Herington (integral test) methods. The binary systems?? vapor-liquid equilibrium data tested by experiments were fitted well with the NRTL, UNIQUAC and Wilson models. The binary interaction parameters regressed by the three models and experimental data were accepted to predict vapor liquid equilibrium data of a ternary system. The maximum absolute deviations and mean absolute deviations between the experimental and thermodynamic model data were within a reasonable range, indicating that corrected binary interaction parameters can be used to accurately predict vapor-liquid equilibrium data of the ternary system. ? 2019 Elsevier Ltd

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