Low loading of Pt on MoB Constructed by microwave Quasi-solid approach with solvent Regulation for hydrogen evolution reaction
关键字：MOLYBDENUM BORIDE; BORON-NITRIDE; NANOPARTICLES
摘要：The interaction between metal nanoclusters and the carrier can enhance the electron transfer rate to optimize the hydrogen evolution reaction (HER) performance, but the common synthesis approaches often lead to metal particle agglomeration, and then blocking active sites. Herein, highly-dispersed Pt nanoclusters supported onto molybdenum boride (MoB) is developed through microwave approach with ious solvent to regulate the catalytic performance. The synthesized electrocatalyst with the addition of methanol (Pt/MoB-M) exhibits excellent electrocatalytic performance towards HER with low overpotential (13 mV at 10 mA cm(-2)), small Tafel slope (24 mV dec(-1)), and high mass activity (10.06 A/mgPt at 50 mV). This work presents a novel approach to prepare highly-efficient electrocatalysts for renewable energy- applications of non-carbon supported low loading of precious metals.
卷号：678
期号：-
是否译文：否