青岛科技大学  English 
王兆波
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教授 硕士生导师  

教师拼音名称:wangzhaobo

学位:工学博士

职称:教授

学科:

材料物理与化学

材料学

材料加工工程

材料科学与工程其他专业

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2019-09-15 山东省优秀教师

2019-05-16 山东省优秀研究生指导教师

2020-12-10 青岛市高校教学名师

2019-09-04 青岛市教书育人楷模

2019-09-15 青岛市新时代最美劳动者

2020-11-10 山东省大学生高分子实用技术大赛“优秀指导教师”

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Non-isothermal Crystallization Kinetics Behavior of Pure Low-density Polyethylene and Low-density Polyethylene/Styrene-butadiene Rubber Thermoplastic Vulcanizates

关键字:VINYL ACETATE COPOLYMER; MORPHOLOGICAL PROPERTIES; PROCESSING CONDITIONS; POLY(LACTIC ACID); CARBON-BLACK; BLENDS; ETHER

摘要:Low-density polyethylene (LDPE)/styrene-butadiene rubber (SBR) thermoplastic vulcanizates (TPV) were prepared by dynamic vulcanization, and the non-isothermal crystallization kinetics of the LDPE/SBR TPV and pure LDPE were investigated by differential scanning calorimetry (DSC), and the crystallization processes of LDPE/SBR TPV and pure LDPE were depicted by the Avrami, Ozawa and Mo equation models. The findings indicated that the crystallization behavior of both LDPE/SBR TPV and pure LDPE can be described by the Mo model and Avrami model modified by the Jeziorny correction, while the Ozawa model was not applicable to describe the behavior. Kinetic data analysis showed that LDPE/SBR TPV had higher crystallization onset temperature (T-0), peak crystallization temperature (T-p), and more stable crystallinity compared to pure LDPE at the same cooling rate.

卷号:61

期号:3

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