教授
硕士生导师
教师拼音名称:wangzhaobo
学位:工学博士
职称:教授
学科:材料物理与化学
材料学材料加工工程材料科学与工程其他专业邮箱:
邮编:
通讯/办公地址:
2019-09-15 山东省优秀教师
2019-05-16 山东省优秀研究生指导教师
2020-12-10 青岛市高校教学名师
2019-09-04 青岛市教书育人楷模
2019-09-15 青岛市新时代最美劳动者
2020-11-10 山东省大学生高分子实用技术大赛“优秀指导教师”
最后更新时间:..
关键字:CROSS-LINKS; POLYMERIZATION; REINFORCEMENT; PROGRESS; SILICA; RUBBER; BONDS; MODEL
摘要:The development of reversible networks in elastomers provided unique inspiration for the design of advanced polymers with excellent properties. In this paper, we adopted an anionic melting method to introduce carboxylate groups into 1,2-polybutadiene (1,2-PB), using maleic anhydride as a modifier, and sodium hydride (NaH), calcium hydride (CaH2), and lithium aluminum hydride (LiAlH4) as metallization reagents. Na-Based, Ca-based, and Li/Al-based ionic bond networks were constructed in the covalently crosslinked 1,2-PB. The effects of the electronegativity and valence of the metal ions on the strength and reversible temperature of the ionic network were studied. Payne effect was shown by rheological tests, demonstrating the interactions between the ionic networks and rubber chains. The reforming temperature for these ionic networks was studied by stress-relaxation analysis, and shape memory experiments were performed based on these temperatures. This concept provides novel inspiration for the design of high-performance and temperature-adaptive elastomers.
卷号:16
期号:15
是否译文:否