关键字:Fluorescence;Charge transfer - Excited states;Complex modes - Fluorescence enhancement - Fluorescence intensities - Fluorescent chemosensor - High selectivity - Intramolecular charge transfers - Schiff-base - Schiff-base derivatives
摘要:A Schiff base derivative, N-(3-methoxy-4-hydroxybenzylidene)salicyloylhydrazone (L), shows high selectivity to Lu<sup>3+</sup>not only in abiotic systems but also in living cells with fluorescence. The presence of PVP can increase the fluorescence intensity. The fluorescence enhancement is presumably due to a combinational effect of intramolecular charge transfer (ICT) and excited-state intra/intermolecular proton transfer (ESPT) during the chelation of L to Lu<sup>3+</sup>in a 2:1 complex mode.<br/> © 2017 The Royal Society of Chemistry.
卷号:9
期号:44
是否译文:否