隋凝

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职务:材料科学与工程学院副院长

学历:博士研究生

办公地点:材料学院209

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A highly selective Schiff base fluorescent chemosensor for Lu<sup>3+</sup>

发布时间:2023-10-19 点击次数:

关键字:Fluorescence;Charge transfer - Excited states;Complex modes - Fluorescence enhancement - Fluorescence intensities - Fluorescent chemosensor - High selectivity - Intramolecular charge transfers - Schiff-base - Schiff-base derivatives
摘要:A Schiff base derivative, N-(3-methoxy-4-hydroxybenzylidene)salicyloylhydrazone (L), shows high selectivity to Lu<sup>3+</sup>not only in abiotic systems but also in living cells with fluorescence. The presence of PVP can increase the fluorescence intensity. The fluorescence enhancement is presumably due to a combinational effect of intramolecular charge transfer (ICT) and excited-state intra/intermolecular proton transfer (ESPT) during the chelation of L to Lu<sup>3+</sup>in a 2:1 complex mode.<br/> &copy; 2017 The Royal Society of Chemistry.
卷号:9
期号:44
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