关键字：HALIDE PEROVSKITE NANOCRYSTALS; LIGHT-EMITTING DEVICES; HIGHLY LUMINESCENT; CSPBI3 NANOCRYSTALS; LEAD; PHASE; LIGAND; EVOLUTION; DIODES
摘要：alpha-CsPbl(3) perovskite quantum dots (PQDs) have great potentials in red-emitting LED and solar cell applications. However, their instability with quick photoluminescence loss with time greatly limits their development. In this study, we found that the nonluminous aged alpha-CsPbl(3) PQDs instantly regained fluorescence emission after a surface treatment with trioctylphosphine. Meanwhile, this surface treatment also worked on fresh alpha-CsPbl(3) PQDs to enhance photoluminescence emission. The structures and compositions of fresh and aged PQDs before and after surface treatment were analyzed in detail. We demonstrated that a surface chemical equilibrium shift mechanism involving oleylammonium led to the PL loss and recovery of alpha-CsPbl(3) PQDs. This chemical equilibrium shift also played an important role in other PQD stabilities against long-term storage, temperature, UV irradiation and ethanol, which were all significantly improved after treatment. The treated alpha-CsPbl(3) PQDs were phase stable for more than 6 months. Oleic acid and oleylamine are common ligands used in PQD syntheses; this study shall promote the understanding of PQD surface chemistry and the preparation of stable alpha-CsPbl(3) PQDs.
卷号：12
期号：10
是否译文：否