论文成果
南海北部大陆架海洋生态系统演变的Ecopath模型比较分析
- 发布时间：2023-10-19
- 点击次数：
- 关键字：OXYGEN REDUCTION; CONTROLLABLE SYNTHESIS; RATE PERFORMANCE; ANODE MATERIALS; ENERGY-STORAGE; CATALYSTS; NANOPARTICLES; COMPOSITES; STABILITY; EVOLUTION
- 摘要：Developing novel hybrid negative electrode materials with high specific capacity, rate capacitance, and long-term cycle stability is a key factor for pushing large-scale application of supercapacitors. However, construction of robust interfaces and low-crystalline active materials plays a crucial role in realizing the target. In this paper, a one-step phosphorization approach was employed to make low-crystalline Fe2P2O7 nanoplates closely bonded to N/P-co-doped graphene nanotubes (N/P-GNTs@b-Fe2P2O7) through interfacial chemical bonding. The N and P heteroatoms as substitutions for C in GNT skeletons can introduce rich electronic centers, which induces Fe2P2O7 to fix the surface of N/P-GNTs through Fe-N and Fe-P bonds as confirmed by the characterizations. Moreover, the lowcrystalline active materials own a disordered internal structure and numerous defects, which not only endows with excellent conductivity but also provides many active sites for redox reactions. Benefiting from the synergistic effects, the prepared N/P-GNTs@b-Fe2P2O7 can not only deliver a high capacity of 257 mA h g(-1) (927 F g(-1)) at 1 A g(-1) but also present an excellent rate capability of 184 mA h g(-1) (665 F g(-1)) at 50 A g(-1) and outstanding cycle stability (similar to 90.6% capacity retention over 40,000 cycles). Furthermore, an asymmetric supercapacitor was assembled using the obtained N/P-GNTs@b-Fe2P2O7 as electrode materials, which can present the energy density as high as 83.3 W h kg(-1) at 791 W kg(-1) and long-term durability. Therefore, this strategy not only offers an effective pathway for achieving high-performance negative electrode materials but also lays a foundation for further industrialization.
- 卷号：14
- 期号：2
- 是否译文：否