郝春成

教授

教授 博士生导师 硕士生导师

职务:先进电工材料研究院院长

学历:博士研究生

主要任职:高压绝缘系统与先进电工材料山东省工程研究中心 主任

其他任职:山东省电工技术学会高压绝缘与电工材料专委会主任委员

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Synthesis of anatase TiO2 with exposed (100) facets and enhanced electrorheological activity

发布时间:2023-10-19 点击次数:

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摘要:Herein, a simple hydrothermal method is employed to synthesize anatase TiO2 with dominant (100) facets, as a precursor, using titanate nanofibers derived from alkali treatment. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD) are carried out to confirm the surface morphology and phase structure of the TiO2 product. The formation mechanism of TiO2 enclosed by (100) and (101) facets is deduced to be the selective adsorption of OH- on the (100) facets of anatase TiO2. Electroheological (ER) experiments indicate that the tetragonal-facet-rod anatase TiO2 with exposed (100) facets exhibits an excellent ER performance with a high ER efficiency of up to 52.5, which results from the anisotropy of its special morphology. In addition, the effect of shape on its dielectric property is investigated via broadband dielectric spectroscopy.
卷号:13
期号:43
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