mu-Adipato-kappa(4) O, O '; O '', O '''-bis[chloro(2,9dimethyl-1,10-phenanthroline-kappa(2) N,N)copper(II)] dihydrate

Release time:2023-10-19 Hits:

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Abstract:In the centrosymmetric title compound, [Cu-2(C6H8O4)(2)Cl-2(C14H12N2) (2)]center dot 2H(2)O, each Cu atom is five-coordinate with a distorted tetragonal-pyramidal geometry. The molecules form stacks with short interplanar distances (3.328 and 3.371 angstrom) between neighbouring phenanthroline ligands, suggesting strong pi-pi interactions. The stacks are arranged in two types of layer, which differ in the direction of the normal to the phenanthroline ligands. The crystal structure is built up from alternating layers of these two types.

Volume:62

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Translation or Not:no