关键字：METAL-CATALYZED SYNTHESIS; KINETIC-THEORY; FAST PYROLYSIS; GRANULAR FLOW; METHYLCHLOROSILANES; CFD; SIMULATION; PARTICLES; RISER; HYDRODYNAMICS

摘要：This paper presents the numerical investigation of the effects of the general bed characteristics such as superficial gas velocities, bed temperature, bed heights and particle size, on the direct synthesis in a 3D fluidized bed reactor. A 3D model for the gas flow, heat transfer, and mass transfer was coupled to the direct synthesis reaction mechanism verified in the literature. The model was verified by comparing the simulated reaction rate and dimethyldichlorosilane (M2) selectivity with the experimental data in the open literature and real production data. Computed results indicate that superficial gas velocities, bed temperature, bed heights, and particle size have vital effect on the reaction rates and/or M2 selectivity.

卷号：5

期号：8827

是否译文：否