关键字：Conducting polymer; Electrochemical copolymerization; Electrochromic devices; 3,4-Ethylenedioxythiophene; Indole

摘要：The spectroelectrochemical and electrochromic properties of a novel copolymer (P(CNIn-co-EDOT)) obtained from 3,4-ethylenedioxythiophene (EDOT) and 5-cyanoindole (CNIn) were discussed. P(CNIn-co-EDOT) can change between purple in the reduced state and blue in the oxidized state. Electrochromic devices (ECDs) based on P(CNIn-co-EDOT) and poly(3,4-ethylenedioxythiophene) (PEDOT) were also fabricated. This as-prepared ECD showed good optical contrast (48% at 630 nm), high coloration efficiency (680 cm(2) C-1), fast response time (0.8 s at 630 nm), good optical memory and long-term stability. Clear change of ECD from brown (reduced state) to dark blue color (oxidized state) was demonstrated with robust cycle life. (C) 2013 Elsevier B.V. All rights reserved.

卷号：700

期号：

是否译文：否