Facile Production of Graphene/Polypropylene Composites with Enhanced Electrical and Thermal Properties through In Situ Artificial Latex Preparation

• Key Words:OXIDE NANOCOMPOSITES; GRAPHENE; NETWORK; GREEN
• Abstract:In order to obtain the unique properties of graphene-based composites, to realize homogeneous dispersion of graphene throughout the polymer matrix remains the key challenge. In this work, edge-oxidized graphene/polypropylene (EOGr/PP) composites with well-dispersed EOGr in PP matrix, synchronously exhibiting high electrical conductivity and thermal property, were simply fabricated for the first time using a novel strategy by in situ artificial PP latex preparation in the presence of EOGr based on solution-emulsification technique. The good dispersion state of EOGr in the PP matrix was demonstrated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). A blue shift in Raman G peak of the EOGr nanosheets was observed in the EOGr/PP composites, indicating the strong interactions between the EOGr nanosheets and the PP matrix. The onset crystallization and crystallization peak temperatures increased as the EOGr loading increases due to its good nucleating ability. An improved thermal stability of EOGr/PP composites was observed as evaluated by TGA. The EOGr/PP composites showed an insulator-to-conductor percolation transition in between that of 1 and 2 wt% EOGr content. Such strategy provides a very effective pathway to fabricate high-performance nonpolar polymer/graphene composites with excellent dispersion state of graphene.
• Volume:2021
• Issue:
• Translation or Not:no