副教授
硕士生导师
教师拼音名称:zhangzhonghua
电子邮箱:
所在单位:新能源材料与器件教研室
学历:博士研究生
办公地点:材料学院楼215A
性别:男
联系方式:15092410550
学位:工学博士
职称:副教授
毕业院校:中国科学院大学
学科:材料科学与工程其他专业
材料学移动电话:
邮箱:
2023-09-15 2023 年度山东省优秀研究生导师
2022-12-30 2022年山东省优秀硕士学位论文指导教师
2022-03-01 2021年度校级先进工作者
2020-06-01 2019年度校级先进工作者
最后更新时间:..
关键字:SOLID-ELECTROLYTE INTERPHASES; ION BATTERIES; PERFORMANCE; CAPACITY; CARBON; NANOSTRUCTURES; PARTICLES; SILICON; STORAGE; DESIGN
摘要:Micro-sized alloy type germanium (Ge) anodes possess appealing properties for next-generation lithium ions batteries, such as desirable capacity, easy accessibility and greater tap density. Nevertheless, volume expansion accompanied by severe pulverization and continuous growth of solid electrolyte interlayer (SEI) still represent fundamental obstacles to their practical applications. Herein, we propose a fresh strategy of constructing robust bond linkage between boron-based coating layer and lithiated polyacrylic acid (PAALi) binder to circumvent the pulverization problems of Ge anodes. Facile pyrolysis of boric acid can introduce an amorphous boron oxide interphase on Ge microparticles (noted as Ge@B2O3). Then in situ crosslinking reaction between B2O3 and PAALi via B-O-C bond linkage constructs a robust Ge anode (Ge@B-PAALi), which is proved by FTIR and Raman characterizations. Post morphological and compositional investigations reveal the minimized pulverization and a thinner SEI composition. The robust bond linkage strategy endows Ge anode with ultra-stable cycling properties of 1053.8 mAh/g after 500 cycles at 1 A/g vs. 500.7 mAh/g for Ge@PAALi and 372.7 mAh/g for Ge@B2O3, respectively. The proposed bond linkage strategy via artificial coating layer and functional binders unlocks huge potential of alloys and other anodes for next-generation battery applications.
卷号:654
期号:-
是否译文:否