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Associate professor

Supervisor of Master's Candidates

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Education Level:博士研究生

Gender:Male

Degree:工学博士

Discipline:Other specialties in Material Science and Engineering
Material Science

张忠华

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Gender:Male

Education Level:博士研究生

Paper Publications

Regulating solvation shells and interfacial chemistry in zinc-ion batteries using glutaronitrile based electrolyte

Key Words:CHALLENGES; SOLVENT; DESIGN
Abstract:The dendrite growth, parasitic reactions and dissolution of cathodes caused by numerous free H2O molecules in aqueous electrolyte can lead to rapid performance degradation, limiting the application of aqueous Zn-ion batteries (AZIBs). Here, a new glutaronitrile (GN) based electrolyte is introduced by coupling a hydrated Zn salt (Zn(ClO4)(2)center dot 6H(2)O) and GN to mitigate these issues. Raman spectroscopy and molecular dynamics simulations demonstrate that the strong coordination between Zn2+ and GN can effectively regulate solvation shells of Zn2+ ions. Moreover, the H2O molecules mostly exist in the confined state rather than in the free state, ensuring the excellent electrochemical performances. Benefiting from this unique solvation shell of Zn2+ ions, Zn||Zn symmetric cells can operate steadily for more than 800 h without Zn dendrite growth, and Zn||Cu half-cells achieve extremely reversible zinc plating/stripping with coulombic efficiencies of 99.0%. XPS suggests that the in situ formed ZnO-rich solid electrolyte interface (SEI) in this GN based electrolyte can effectively inhibit the occurrence of parasitic reactions, improving the stability of the battery. Thus, the Zn||NH4V4O10 full cells exhibit a high specific capacity of 239 mA h g(-1) at 5C over 2500 cycles without significant capacity decay. The differences in the electrochemical reaction mechanism of the NH4V4O10 cathode in between ZHO and ZGN have been discussed in detail.
Volume:10
Issue:27
Translation or Not:no