Personal Homepage

Personal Information

MORE+

Associate professor

Supervisor of Master's Candidates

E-Mail:

Education Level:博士研究生

Gender:Male

Degree:工学博士

Discipline:Other specialties in Material Science and Engineering
Material Science

张忠华

+

Gender:Male

Education Level:博士研究生

Paper Publications

Fast anion intercalation into graphite cathode enabling high-rate rechargeable zinc batteries

Key Words:Secondary batteries;Anodes - Battery storage - Cathodes - Charging (batteries) - Costs - Electrolytes - Graphite - Ions - Metallic compounds - Metals
Abstract:Cheap, high-rate and long-life batteries are urgently needed for grid-scale storage of renewable energy. Rechargeable zinc (Zn) batteries are potential candidates due to the high volumetric energy density and low cost of Zn anode. However, conventional Zn batteries employing metal oxide cathodes usually suffer from poor rate capabilities caused by the high migration barrier of Zn<sup>2+</sup> in the metal oxide host structure. Here, we circumvent this dilemma by integrating Zn electrochemistry with bis(trifluoromethanesulfonyl) imide (TFSI<sup>−</sup>) anion (de)intercalation into graphite cathode based on a Zn(TFSI)<inf>2</inf>/acetonitrile electrolyte. Owing to the fast intercalation of TFSI<sup>−</sup> along with the efficient Zn/Zn<sup>2+</sup> redox kinetics, our Zn/graphite batteries enable an ultrafast charging rate up to 200C (to be fully charged in 18 s) and deliver a high power density of 16.3 kW kg<sup>−1</sup>, which is comparable to those of supercapacitors. Besides, the rational utilization of the acetonitrile-based electrolyte further endows the resultant battery with dendrite-free Zn deposition, high voltage output (>2.2 V) as well as wide-temperature adaptability from −40 to 80 °C, which is quite promising for grid-scale energy storage. Our work opens a new avenue for building high-rate low-cost batteries through coupling anion intercalation chemistry with multivalent metal anodes.<br/> © 2020 Elsevier B.V.
Volume:457
Issue:wu
Translation or Not:no