Key Words:THERMAL INSULATION; SILICA; ADSORPTION; WATER
Abstract:The aim of this study was to achieve rapid gelation of chitosan (CS) and silica (SA) without crosslinking agent, the relationship between process parameters and the composite aerogels properties were also explored. By ying the composition ratio of the system (from SA:CS = 1:1 to 5:1), the system gelation time was reduced by >12 times, and the drying shrinkage of the composite aerogel reached a minimum of 7.6 %. During the two recombination processes, chitosan rapidly formed aqueous colloid secondary structure under the influence of ethanol. This phenomenon reduced the stability of the system and allowed silica to form a two-phase composite hydrogel. Because the network gap between the fibers was used as a limiting medium for gel growth. In addition, the chitosan/silica composite aerogels exhibited a mesoporous structure with low density (0.1144 g/cm(3)), and the thermal conductivity was 0.028 W/(m<middle dot>K) at 30 degrees C. The trimethylchlorosilane made the composite aerogel have good hydrophobicity with water contact angle as 134.7 degrees, and the adsorption capacity of carbon tetrachloride could reach >10 times of its own weight. This study provides an eco-friendly and high-efficiency method for preparing aerogels, which has potential applications in the fields of thermal insulation, oil-water separation, etc.
Volume:264
Issue:子辑2
Translation or Not:no