Key Words:SUPERCRITICAL CARBON-DIOXIDE; MECHANICAL-PROPERTIES; HEAT-TRANSFER; PLA; CRYSTALLIZATION; POLYSTYRENE; IMPROVEMENT; STATE; MELT
Abstract:In this study, a fully biodegradable ultra-light poly(lactic acid)/silicon dioxide (PLA/SiO2) aerogel nano composite with ultra-low thermal conductivity was successfully fabricated. PLA used was a produced from lactic acid, where the lactic acid has been produced from carbohydrates. The rheological properties of PLA were enhanced by diphenylmethane diisocyanate (MDI). The foaming properties, cell density, cell size uniformity, mechanical properties and thermal conductivity and thermal diffusivity of PLA were further improved by SiO2 aerogel, and finally the ultra-low density foamed material was prepared by supercritical CO2. The density of PLA foam can be as low as 0.02 g/cm(3) and the thermal conductivity as low as 0.02628 W/m center dot K. The PLA-based composites can be used in many fields such as thermal insulation, vibration damping and packaging, and can be fully biodegradable and sustainable throughout their life cycle, which meets the global trend of energy saving and emission reduction.
Volume:192
Issue:
Translation or Not:no