Breaking the diffusion coefficient limitation of bismuth oxide anodes for aqueous alkaline batteries with ultra-high rate capability
关键字:amorphous/crystalline structuresaqueous alkaline rechargeable batteriesBi nanoflakesheterostructureultrahigh capacity
摘要:Although various bismuth (Bi) electrode materials are reported to assemble aqueous alkaline rechargeable batteries (AARBs) owing to desirable potential window and high theoretical capacity, the Bi-based electrode materials are still confronted with by their "death space" and poor stability. Herein, a zero-dimensional/two-dimensional (0D/2D) amorphous/crystalline BiOx-Bi heterostructure is successfully synthesized by a one-step reduction method for achieving nearly theoretical capacity. Under proper NaBHNaBH4 content, the Bi33+ is reduced to form ultra-thin 2D metallic bismuth nanoflakes (Bi-nf), and incompletely reduced amorphous 0D BiOx nanodots are embedded in Bi-nf to form the target BiOx/Bi-nf heterostructure. The embedded 0D nanodots inhibit the aggregation of 2D Bi-nf, accelerate the mass transport rate with more oxygen vacancies and pores at heterogeneous interface, and the active centers of amorphous nanodots and ultrathin nanoflakes are recognized as completely accessible which is benefit for up to theoretical capacity. Accordingly, the optimized 0D/2D amorphous/crystalline BiOx-Bi-nf heterostructure electrode presents an admirable capacity of 350 mAh g-1 at 1 A g-1 and outstanding capacity retention of 79.9% at 20 A g-1. Moreover, the assembled BCNP (basic cobalt/nickel phosphate)//BiOx/Bi-nf battery exhibits exceptional energy density of 191.64 Wh kg-1 at 1.28 kW kg-1 power density and durable stability (80% after 14000 cycles). Herein, an amorphous BiOx nanodots embedded metallic bismuth nanoflakes 0D/2D heterostructure (BiOx/Bi-nf) with nearly theoretical capacity are successfully synthesized by a facile one-step reduction method. The assembled BCNP//BiOx/Bi-nf (BCNP: basic cobalt/nickel phosphate core-shell microsphere) device reveals a superior capacitance retention of 80% after 14,000 cycles and outstanding energy density of 191.64 Wh kg-1 at 1.28 kW kg-1. image
卷号:34
期号:48
是否译文:否