青岛科技大学  English 
张建明
赞  

教师拼音名称:zhangjianming

手机版

访问量:

最后更新时间:..

Effect of cellulose solubility on the thermal and mechanical properties of regenerated cellulose/graphene nanocomposites based on ionic liquid 1-allyl-3-methylimidazoliun chloride

关键字:

摘要:Regenerated cellulose/ionic liquids (ILs)-reduced graphene oxide (IRGO) nanocomposites have been prepared via a simple and green method based on 1-allyl-3-methylimidazoliun chloride (AmimCl). To one's surprise, it is found that the presence of a small amount of IRGO sheets can largely decelerate the dissolution of cellulose in AmimCl, and thus the thermal and mechanical properties of resultant cellulose/IRGO nanocomposites could be controlled simply by changing the dissolution time. Our results suggest that the residual cellulose fibrils with micrometre size are beneficial to the thermal stabilities of regenerated cellulose/IRGO films when short dissolution time is used. However, for obtaining cellulose/IRGO nanocomposites with improved mechanical properties, full dissolution and mixture of cellulose in IRGO/AmimCl solution with prolonged time are required. Compared with the regenerated pure cellulose film, our cellulose/IRGO nanocomposite prepared with dissolution time of 4 h exhibits about 23 degrees C increase in decomposition temperature, and 10.7% increase in tensile strength and remarkably 387.5% increase in strain at break, respectively.

卷号:5

期号:93

是否译文:

崂山校区 - 山东省青岛市松岭路99号   
四方校区 - 山东省青岛市郑州路53号   
中德国际合作区(中德校区) - 山东省青岛市西海岸新区团结路3698号
高密校区 - 山东省高密市杏坛西街1号   
济南校区 - 山东省济南市文化东路80号©2015 青岛科技大学    
管理员邮箱:master@qust.edu.cn