青岛科技大学  English 
张建明
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教师拼音名称:zhangjianming

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Creating thermal conductive pathways in polymer matrix by directional assembly of synergistic fillers assisted by electric fields

关键字:BORON-NITRIDE; COMPOSITES; GRAPHITE; NANOCOMPOSITES; ENHANCEMENT; MANAGEMENT; GRAPHENE

摘要:Large amount of heat accumulated within the increasingly miniaturized electronic equipment negatively affects their device accuracy and service life, which can also cause potential environmental hazards and safety concerns. In this work, a strategy of creating thermal conductive pathways using micro-sized boron nitride (BN) and nano -sized alumina (Al2O3) in polydimethylsiloxane (PDMS) matrix by the application of electric fields was demon-strated. The synergistic effect between two distinct particles enables the improved thermal conductivity of the BN/Al2O3/PDMS composites, which can be further enhanced by directional assembly of these fillers under electric fields. At the same filler loading content, the thermal conductivity of aligned ternary composite is 0.228 W/mK, which is higher than the random composites (0.215 W/mK), as well as their counterparts containing only a filler type (0.196 W/mK and 0.172 W/mK for BN/PDMS and Al2O3/PDMS composites, respectively). Furthermore, chain-like pathways from assembled fillers can improve the dielectric permittivity of the com-posites up to 6.6, while the dielectric loss remains at a low value (<0.1). Overall, this works provides a simple and effective strategy for manufacturing ternary polymer composites with improved thermal and dielectric properties through controlling the orientation of fillers. <comment>Superscript/Subscript Available</comment

卷号:35

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