青岛科技大学  English 
张建明
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教师拼音名称:zhangjianming

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Ultrafine and carboxylated ??-chitin nanofibers prepared from squid pen and its transparent hydrogels

关键字:Shellfish;Acetylation - Ammonium persulfate - Calcite - Calcium carbonate - Carboxylation - Chitin - Disintegration - Hydrogels - Molluscs - Nanofibers

摘要:TEMPO-mediated oxidation has been successfully used to prepare carboxylated chitin nanofibers (ChNFs) with purified chitins originating from the outer shells of crab and shrimp (&alpha;-form) or tubeworm (&beta;-form). However, the method for obtaining carboxylated ChNFs with squid pen chitin (hydrated &beta;-form) has not been developed yet. It might be due to the existence of the small amount of partial deacetylation (DD &asymp; 9%) in the squid pen &beta;-chitins. Herein, ultrafine (2&ndash;4 nm in width and several micrometers in length) and carboxylated &beta;-ChNFs were fabricated directly from the squid pen with simultaneously removing of protein, CaCO3 and other non-chitin components by one-step oxidation procedure using ammonium persulfate (APS) and followed ultrasonic disintegration under acid conditions. When 45 wt% APS was used to react with squid pen, the carboxylate content of ChNFs reaches 0.802 mmol/g. Therefore, the &beta;-ChNFs with anionically charged groups (COO<sup>&minus;</sup>) can be dispersed stably in aqueous solution under basic conditions. Meanwhile, thus-obtained &beta;-ChNFs aqueous solution even with very low concentration (0.8%) can be transformed to transparent, robust and moldable hydrogels by gas coagulation of acetic acid.<br/> &copy; 2019 Elsevier Ltd

卷号:211

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