Silica aerogel-PVA dough: A high internal phase composite with superior thermal insulation and gas barrier

Key Words:FABRICATION; COATINGS; OXYGEN

Abstract:Silica aerogel (SA) has shown great promise in constructing thermal insulation composites in various forms. However, it is still challenging to disperse a huge amount of SA particles into other matrices for fabricating superior thermal insulation materials or highly filled masterbatch, owing to its high specific surface area and ultra -low density. Herein, inspired by high internal phase emulsion (HIPE), we successfully prepare processable SA/polyvinyl alcohol (PVA) composites (SA-PVA dough) with over 74 vol% dispersed SA, using a PVA aqueous solution as a binder. This is achieved by gradually mixing a large amount of hydrophobic SA filler into a small amount of PVA aqueous solution. The resulting SA-PVA dough exhibits an internal structure resembling that of HIPEs, with hydrophobic SA particles stabilized in the water phase by amphiphilic PVA chains, tightly packed within the thin continuous PVA aqueous phase. Benefiting from such a HIPE structure, the SA-PVA dough can be easily shaped into various forms and exhibits good applicability in further processing. The dried dough inherits the excellent properties of SA, including ultra -low density, superhydrophobicity (water contact angle: 153 degrees ), thermal insulation (thermal conductivity: 0.03 W m -1 K -1 ), and flame resistance. Moreover, the continuous PVA network structure, combined with the nanoscale pore structure of SA, provides the dough with excellent gas barrier properties, greatly expanding the application scope of SA -based composites.

Volume:251

Issue:

Translation or Not:no