论文成果
Miscibility of isotactic poly(1-butene)/isotactic polypropylene blends studied by atomic force Microscopy-Infrared
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关键字:CRYSTAL-CRYSTAL TRANSITION; CRYSTALLIZATION BEHAVIOR; POLYBUTENE-1; TRANSFORMATIONS; AFM; NUCLEATION; KINETICS; DOMAINS
摘要:In this work, miscibility behavior of blends of high molecular weight isotactic poly(1-butene) (PB) and isotactic polypropylene (PP) has been investigated by atomic force microscopy-infrared (AFM-IR) technique. A PP with 10 mol% deuterated units (dPP) was mixed with the PB at 50/50 mass ratio and the melt was found to phase separate, and the distinct C-D stretching bands of the dPP were observed in both phases by AFM-IR, indicative of partial miscibility of the two polymers. By using an AFM-IR quantitative analysis method, PB content in each phase in PB/PP blends can be determined. The phase separation kinetics of a PB/PP 50/50 blend was investigated, and the compositions of the two co-existing phases at equilibrium at different temperatures were determined by AFM-IR, from which a phase diagram was constructed. The PB/PP blends were found to exhibit lower critical solution temperature-type phase behavior, with the critical temperature of around 160 C by estimate.
卷号:239
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张春雨

教授 博士生导师 硕士生导师

教师拼音名称:zhangchunyu

出生日期:1978-11-30

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入职时间:2019-11-28

所在单位:先进橡胶材料教育部重点实验室

学历:博士研究生

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性别:男

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学位:理学博士

毕业院校:吉林大学

所属院系:先进橡胶材料教育部重点实验室

学科:材料科学与工程其他专业
高分子化学与物理

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