- Effect of gasifying medium on the coal chemical looping gasification with CaSO<inf>4</inf>as oxygen carrier
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- 关键字：Sulfur compounds;Activation energy - Calcium compounds - Carbon dioxide - Chemical reactors - Coal - Cracking (chemical) - Fuels - Gasification - Oxygen - Synthesis gas;Chemical looping - Chemical-looping process - Iso-conversional method - Oxygen Carrier - Reaction mechanism - Syn-gas generation - Thermodynamical analysis - Thermogravimetric analyzers
- 摘要：The chemical looping gasification uses an oxygen carrier for solid fuel gasification by supplying insufficient lattice oxygen. The effect of gasifying medium on the coal chemical looping gasification with CaSO<inf>4</inf>as oxygen carrier is investigated in this paper. The thermodynamical analysis indicates that the addition of steam and CO<inf>2</inf>into the system can reduce the reaction temperature, at which the concentration of syngas reaches its maximum value. Experimental result in thermogravimetric analyzer and a fixed-bed reactor shows that the mixture sample goes through three stages, drying stage, pyrolysis stage and chemical looping gasification stage, with the temperature for three different gaseousmedia. The peak fitting and isoconversional methods are used to determine the reaction mechanism of the complex reactions in the chemical looping gasification process. It demonstrates that the gasifying medium (steam or CO<inf>2</inf>) boosts the chemical looping process by reducing the activation energy in the overall reaction and gasification reactions of coal char. However, themechanism using steamas the gasifying medium differs from that using CO<inf>2</inf>. With steam as the gasifying medium, parallel reactions occur in the beginning stage, followed by a limiting stage shifting from a kinetic to a diffusion regime. It is opposite to the reaction mechanism with CO<inf>2</inf>as the gasifying medium.<br/> © 2014 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.
- 卷号：22
- 期号：11
- 是否译文：否
