Synthesis of nanostructured MnO<inf>2</inf>, SnO<inf>2</inf>, and Co<inf>3</inf>O<inf>4</inf>: graphene composites with enhanced microwave absorption properties

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Abstract:In this work, metal oxide (MnO<inf>2</inf>, SnO<inf>2</inf> and Co<inf>3</inf>O<inf>4</inf>)–graphene composite materials were successfully prepared via different synthesis methods. Uniform metal oxide nanoparticles were well dispersed on graphene sheets, and transmission electron microscopy characterizations showed that the average sizes of MnO<inf>2</inf>, SnO<inf>2</inf>, and Co<inf>3</inf>O<inf>4</inf> particles were about 60, 5, and 10 nm, respectively. Reflection losses of graphene composites and pure graphene were systematically evaluated between 2 and 18 GHz, which revealed that all composites exhibited enhanced microwave absorption properties compared to pure graphene. The minimum reflection losses of MnO<inf>2</inf>-graphene, SnO<inf>2</inf>–graphene, and Co<inf>3</inf>O<inf>4</inf>–graphene composites with a thickness of 2.0 mm were −20.9, −15.28, and −7.3 dB at the frequency of 14.8, 15.94, and 9.6 GHz, respectively, whereas −4.5 dB for pure graphene. The enhanced absorption ability probably originated from the combined advantage of metal oxide particles and graphene, which proved beneficial to improve the impedance matching of permittivity and permeability. Besides, the intrinsic characteristics of MnO<inf>2</inf>, SnO<inf>2</inf>, and Co<inf>3</inf>O<inf>4</inf> nanoparticles, the interface between nanostructured metal oxides and graphene sheets, and the multi-dielectric relaxation processes are all influence factors to improve the properties of microwave absorption. © 2015, Springer-Verlag Berlin Heidelberg.

Volume:119

Issue:4

Translation or Not:no