Hydrogen generation from catalytic hydrolysis of sodium borohydride solution using supported amorphous alloy catalysts (Ni-Co-P/γ-Al<inf>2</inf>O<inf>3</inf>)
关键字：Hydrogen production;Activation energy - Amorphous alloys - Atomic emission spectroscopy - Catalysts - Electroless plating - Gas adsorption - Hydrolysis - Inductively coupled plasma - Nitrogen plasma - Scanning electron microscopy - Sodium Borohydride - Spectrometers - X ray diffraction - X ray spectrometers;Amorphous alloy catalyst - Borohydride solutions - Energy dispersive x-ray spectrometers - Field emission scanning electron microscopes - Hydrogen generations - Inductively Coupled Plasma Atomic Emission Spectrometers - Morphology and structures - Nitrogen adsorption desorption isotherms
摘要：The supported amorphous alloy catalysts Ni-Co-P/γ-Al<inf>2</inf>O<inf>3</inf>were synthesized by electroless plating for hydrogen generation from catalytic hydrolysis of sodium borohydride solution. The influences of deposition time, pH, NaBH<inf>4</inf>concentration and the Co/Ni atomic ratio on the hydrogen generation rate were investigated in this paper. The reported work also includes the full experimental details for the collection of a wealth of kinetic data to determine the activation energy (E<inf>a</inf>= 52.05 kJ mol<sup>-1</sup>). Energy dispersive X-ray spectrometer (EDS), field emission scanning electron Microscope (SEM), inductively coupled plasma-atomic emission spectrometer (ICP-AES) and X-ray diffraction (XRD), nitrogen adsorption-desorption isotherm were used to characterize surface element composition, morphology and structure of the amorphous alloy. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.<br/>
卷号：39
期号：27
是否译文：否