Properties of Cu–Co–P/Γ-Al<inf>2</inf>O<inf>3</inf>catalysts for efficient hydrogen generation by hydrolysis of alkaline NaBH<inf>4</inf>solution
关键字：Hydrogen production;Activation energy - Alkalinity - Atomic emission spectroscopy - Catalysts - Deposition - Electroless plating - Energy dispersive spectroscopy - Hydrolysis - Inductively coupled plasma - Scanning electron microscopy - Spectrometers - X ray diffraction;Characterization methods - Chemical compositions - Energy dispersive spectroscopies (EDS) - Hydrogen generations - Inductively Coupled Plasma Atomic Emission Spectrometers - Low-activation energy - NaBH<inf>4</inf> - Sodium boro hydrides
摘要：The catalytic properties of Cu–Co–P/γ-Al<inf>2</inf>O<inf>3</inf>in hydrogen production via sodium borohydride hydrolysis were investigated on aspects of the surface morphology, structure and chemical composition. The characterization methods employed are X-ray diffraction (XRD), scanning electron microscope (SEM), inductively coupled plasma-atomic emission spectrometer (ICP-AES) and energy dispersive spectroscopy (EDS). The amorphous Cu–Co–P/γ-Al<inf>2</inf>O<inf>3</inf>alloy catalyst was synthesized by electroless deposition. It was found that the as-prepared catalysts exhibited low activation energy (E<inf>a</inf> = 47.8 kJ mol<sup>−1</sup>) and good cycle properties in catalytic hydrolysis of NaBH<inf>4</inf>solution. The influences of NaOH and NaBH<inf>4</inf>concentration and temperature on hydrogen generation rate (HRG) were also investigated in this paper. © 2016 Hydrogen Energy Publications LLC
卷号：42
期号：9
是否译文：否