谢广文   Professor

谢广文,教授,博士,长期从事纳米材料、微晶与非晶态材料研究与应用,在纳米材料表面改性、非晶态催化材料等领域取得了许多创新性成果。近年来在《燃料化学学报》、Chemical Engineering Journal、Carbon、Green Energy & Environment、Journal of Materials Chemistry A、Applied Surface Science、 ACS Applied Materials & Interfaces、Journal of Power Sources、Renewable Energy、Surface and Coatings Technolo...Detials

Properties of Cu-Co-P/gamma-Al2O3 catalysts for efficient hydrogen generation by hydrolysis of alkaline NaBH4 solution

Release time:2021-03-15  Hits:

  • Key Words:Electroless deposition; NaBH4; Catalysts; Hydrolysis
  • Abstract:The catalytic properties of Cu-Co-P/gamma-Al2O3 in hydrogen production via sodium borohydride hydrolysis were investigated on aspects of the surface morphology, structure and chemical composition. The characterization methods employed are X-ray diffraction (XRD), scanning electron microscope (SEM), inductively coupled plasma-atomic emission spectrometer (ICP-AES) and energy dispersive spectroscopy (EDS). The amorphous Cu-Co-P/gamma-Al2O3 alloy catalyst was synthesized by electroless deposition. It was found that the as. prepared catalysts exhibited low activation energy (E-a = 47.8 kJ mol(-1)) and good cycle properties in catalytic hydrolysis of NaBH4 solution. The influences of NaOH and NaBH4 concentration and temperature on hydrogen generation rate (HRG) were also investigated in this paper. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
  • Volume:42
  • Issue:9
  • Translation or Not:no