Morphology and electrokinetic behavior of styrene-2-ethylhexyl acrylate copolymer latex for coatings prepared by two-stage seeded emulsion polymerization

• Key Words:AQUEOUS-SOLUTION; GRAPHENE OXIDE; PERFORMANCE; COMPOSITES; PHOSPHATE; CATALYST; NANOPARTICLES; OXIDATION; CHROMIUM; ISOTHERM
• Abstract:Cerium-based adsorbents possessed unique advantages of valence iability and abundant oxygen vacancies in hexavalent chromium (Cr(VI)) adsorption, but high cost and unstable properties restricted their application in Cr (VI) contained wastewater treatment. Herein, a series of bimetallic adsorbents with different cerium/iron ratios (CeFe@C) were prepared by adding inexpensive Fe into Ce-based adsorbents (Ce@C), and the effect of Fe doping on adsorption properties of Ce@C for Cr(VI) was investigated thoroughly. Compared with pristine Ce@C, CeFe@C exhibited excellent removal performance for Cr(VI), and the improved maximum adsorption capacity reached 75.11 mg/g at 25degree celsius. Benefiting from Fe doping, CeFe@C had good regeneration property, with only 25 % decrease after five adsorption-desorption cycles. Contents of trivalent cerium (Ce(III)) and oxygen vacancies (Ov) in bimetallic adsorbents were positively cor with divalent iron (Fe(II)) doping, indicating that the formation of Ce(III) and surface defects on Ce@C could be effectively regulated by Fe doping. Density functional theory (DFT) calculation results further proved that the doped Fe enhanced the electron transfer effectively and
• Volume:673
• Issue:无
• Translation or Not:no