青岛科技大学主页平台管理系统 WL--Home-- CH3NH2 gas induced (110) preferred cesium-containing perovskite films with reduced PbI6 octahedron distortion and enhanced moisture stability

王莉

Associate professor

Supervisor of Master's Candidates

Date of Employment:2006-07-14

Team member

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CH3NH2 gas induced (110) preferred cesium-containing perovskite films with reduced PbI6 octahedron distortion and enhanced moisture stability

Release time:2023-10-19 Hits:

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Abstract:We report here the discovery of a fancy interaction between cesium iodide (CsI) and methylamine (CH3NH2) due to the presence of the hydrogen bond. The formed CsI center dot xCH(3)NH(2) is a liquid phase, which facilitates the large scale fabrication of highly uniform cesium-containing perovskite films with strong (110) preferred orientation by the CH3NH2 gas healing process. With this method, at most 10% nonpolar Cs cations could fully dope into the crystal lattice and extremely enhance the interaction of the inorganic framework with a more symmetrical PbI6 octahedron, resulting in obvious improvement in moisture stability under continuous illumination.

Volume:5

Issue:10

Translation or Not:no

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