Key Words:modification; metal complex; platinum; selective hydrogenation; chlorobenzene
Abstract:The metal complex effect on the hydrogenation of chlorobenzene over a poly(N-vinyl-2-pyrrolidone)-stabilized platinum colloidal nanocatalyst (PVP-Pt) has been studied under 298 K and atmospheric pressure. The introduction of metal complexes and ligands exhibited great effect on the activity and the selectivity of the nanocatalyst. It is evidently manifested that the modification of metal complexes is not the simple sum of those of the metal central ions and the corresponding ligands.
Volume:46
Issue:6
Translation or Not:no