汪恕欣

博士生导师 硕士生导师

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Constructing perfect cubic Ag-Cu alloyed nanoclusters through selective elimination of phosphine ligands

发布时间:2024-03-08 点击次数:

关键字:NANOPARTICLES; CONVERSION; MECHANISM
摘要:The aspiration of chemists has always been to design and achieve control over nanoparticle morphology at the atomic level. Here, we report a synthesis strategy and crystal structure of a perfect cubic Ag-Cu alloyed nanocluster, [Ag55Cu8I12(S-C6H32,4(CH3)2)24][(PPh4)] (Ag55Cu8I12 for short). The structure of this cluster was determined by single-crystal X-ray diffraction (SCXRD) and further validated by X-ray photoelectron spectroscopy (XPS), inductively coupled plasma (ICP), Energy-dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), and 1H and 31P nuclear magnetic resonance (NMR). The surface deviation of the cube was measured to be 0.291 angstrom, making it the flattest known cube to date. The aspiration of chemists has always been to design and achieve control over nanoparticle morphology at the atomic level.
卷号:26
期号:1
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