Release time:2023-10-19  Hits:

• Key Words:HIGH-PERFORMANCE SUPERCAPACITORS; ELECTRODE MATERIAL; KOH ACTIVATION; HYDROTHERMAL CARBONIZATION; BIOMASS WASTE; NITROGEN; ENERGY; HYBRID; NANOSHEETS; GRAPHENE
• Abstract:In order to improve electrochemical capacitance properties of biomass-derived porous carbon materials, this work develops a low temperature pre-carbonization, hydrothermal stabilization and KOH activation method to derive N, O, P, S co-doped porous carbon materials from protein-rich soybeans and effectively enhances specific capacitances in both acidic and alkaline aqueous electrolytes. Specially, the derived porous carbon demonstrates an ultra-high specific capacitance of 685.1 F g(-1) at 0.5 A g(-1) in 2 M KOH and 439.5 F g(-1) at 1 A g(-1) in 1 M H2SO4, respectively. Moreover, a superior cycling stability is achieved with a capacitance retention of 80% after 13,000 cycles at a current density of 20 A g(-1) in 2 M KOH. An asymmetric supercapacitor consisting of soybean-derived carbon and NiCo-sulfide delivers a high energy density of 41.8 Wh kg(-1) at a power density of 750 W kg(-1). The findings above indicate hydrothermal process can effectively stabilize heteroatoms (N and P), improve graphitization and thereby enhance capacitive properties of biomass-derived carbon materials. (C) 2020 Elsevier Ltd. All rights reserved.
• Volume:163
• Issue:wu
• Translation or Not:no