One-pot synthesis of 2-ethylanthraquinone from phthalic anhydride and ethylbenzene over a Sc-modified H beta catalyst

• Key Words:HIGHLY EFFICIENT; ZEOLITE-BETA; ACID; ANTHRAQUINONE; ACYLATION; CONVERSION; INSIGHTS; METALS; CU
• Abstract:2-Ethylanthraquinone is frequently used for producing bulk consuming chemicals. However, the synthesis of 2-ethylanthraquinone is still restricted by expensive raw materials, complex preparation process and poor-cycling catalyst. Herein, a one-pot method is developed to synthesize 2-ethylanthraquinone using phthalic anhydride and ethylbenzene as feedstock by combination of acylation and dehydration over a Sc-modified H beta catalyst. Sc-modified H beta was prepared via impregnation and catalyzed conversion of phthalic anhydride about 58.8% and 2-ethylanthraquinone selectivity up to 78.5% which is better than the results by other metals-modified H beta zeolites. By adjusting Sc loading amount in H beta, more acids are created especially strong Lewis acid and an appropriate synergistic effect of Lewis/Bronsted acids is obtained for cascade reactions of acylation and dehydration. Then, the reaction conditions were investigated and the catalyst can be reused in 4 runs. This work provides a green and simple way for 2-ethylanthraquinone synthesis. (C) 2022 Published by Elsevier Ltd.
• Volume:251
• Issue:
• Translation or Not:no