工学博士

博士研究生

Personal Information

E-Mail:

VIEW MORE

Other Contact Information:

Email :


Home > Scientific Research > Paper Publications

Modulating electronic structure and sulfur p-band center by anchoring amorphous Ni@NiS<sub>x</sub> on crystalline CdS for expediting photocatalytic H<sub>2</sub> evolution

Release time:2024-01-19 Hits:

Key Words:HETEROSTRUCTURE
Abstract:Photocatalytic water splitting is a prospective approach to address the energy and environmental challenges. Herein, an amorphous Ni@NiSx cocatalyst has been fabricated and simultaneously assembled onto CdS to form amorphous-crystalline Ni@NiSx-CdS photocatalyst via a partial reduction strategy. Comprehensive experiments and theoretical calculations demonstrate that the synergistic effects between the electronic coupling of amorphous-crystalline interface and the gradient work function iation induced by Ni nanocluster encapsulation achieve the deeper downshift of the S p-band center to optimize H* intermediate adsorption, enhance charge extraction ability though Schottky junction and lower H* adsorption Gibbs free energy (Delta G(H*)). Accordingly, the optimal Ni@NiSx-CdS photocatalyst delivers a remarkable photocatalytic H-2 production rate of 78.7 mmol.g(-1).h(-1) with an apparent quantum efficiency (AQE) of 36.74% at 420 nm, which is approximately 18.3 and 1.5 times than that of CdS and NiSx-CdS, respectively. This work offers a novel insight into the development of amorphous nanocomposite cocatalysts for promoting solar-to-H-2 energy conversion.
Volume:342
Issue:
Translation or Not:no