青岛科技大学  English 
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教授 博士生导师  
硕士生导师  

教师拼音名称:linjianjian

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入职时间:2018-09-11

所在单位:化学与分子工程学院

学历:博士研究生

办公地点:四方校区第一实验楼216

性别:女

联系方式:19862229511

学位:工学博士

职称:教授

毕业院校:澳大利亚伍伦贡大学

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Enhancing low temperature properties through nano-structured lithium iron phosphate and solid liquid interface control by LATP

关键字:ION CONDUCTIVITY; ELECTROLYTE

摘要:Lithium iron phosphate battery works harder and lose the vast majority of energy and capacity at the temperature below-20 degrees C, because electron transfer resistance (Rct) increases at low-temperature lithium-ion batteries, and lithium-ion batteries can hardly charge at-10 degrees C. Serious performance attenuation limits its application in cold environments. In this paper, according to the dynamic characteristics of charge and discharge of lithium-ion battery system, the structure of lithium iron phosphate is adjusted, and the nano-size has a significant impact on the low-temperature discharge performance. The primary particle size of the material synthesized by the hydrothermal method is about 140 nm, and the discharge capacity under-20 degrees C is 93 % than that of the capacity discharged under 25 degrees C. The conductivity is in connection with the concentration of the electrolyte, and the application of highly concentrated liquid electrolyte and the addition of lithium-ion conductive material Li 1.3 Al 0.3 Ti 1.7 (PO4)3(LATP) in the positive electrode, the discharge capacity is more than 50 % at ultra-low temperature-60 degrees C compares to the capacity released at 25 degrees C.

卷号:1010

期号:

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