青岛科技大学  English 
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学历:博士研究生

学位:理学博士

毕业院校:山东大学

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The reduction of Eu<sup>3+</sup>to Eu<sup>2+</sup>in a new orange-red emission Sr<inf>3</inf>P<inf>4</inf>O<inf>13</inf>: Eu phosphor prepared in air and its photoluminescence properties

关键字:Strontium compounds;Citrus fruits - Europium - High temperature applications - Luminescence - Optical materials - Phosphors - Photoluminescence - Solid state reactions - X ray powder diffraction;Charge compensation - High temperature solid-state reaction - Orange-red - Orange-red phosphor - Photoluminescence properties - Photoluminescence spectrum - Triclinic systems - WLEDs

摘要:A new orange-red phosphor Sr<inf>3</inf>P<inf>4</inf>O<inf>13</inf>: Eu was synthesized by a high temperature solid-state reaction. X-ray powder diffraction (XRD) analysis confirms the formation of Sr<inf>3</inf>P<inf>4</inf>O<inf>13</inf>in a triclinic system with space group P1&macr;. The photoluminescence spectra indicate that Sr<inf>3</inf>P<inf>4</inf>O<inf>13</inf>: Eu can be excited effectively by near ultraviolet (NUV) light and exhibit bright orange-red emission with excellent color stability. Interestingly, the emission bands of Eu<sup>2+</sup>and Eu<sup>3+</sup>were both observed in the photoluminescence spectra of air-sintered Sr<inf>3</inf>P<inf>4</inf>O<inf>13</inf>: Eu phosphor due to the self-reduction effect. This kind of abnormal reduction was explained by a charge compensation model. &copy; 2014 Elsevier Ltd and Techna Group S.r.l.<br/>

卷号:40

期号:6

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