青岛科技大学  English 
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副教授 硕士生导师  

教师拼音名称:Lichengdong

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办公地点:材料科学与工程学院229房间

性别:男

联系方式:15588619659

职称:副教授

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Selectivity diversity for a single cobalt(II) precatalyst mediated butadiene polymerization

关键字:AL-SI ALLOY; PERFORMANCE; CATALYST

摘要:Owing to the combined advantages of Al-Si alloy and Al2O3, Al-Si@Al2O3 is widely utilized as a heat storage material, catalyst carrier, and water adsorption host. Hence, the preparation of Al-Si@Al2O3 and corresponding precursors is of utmost significance. Herein, an Al-Si@Al(OH)(3) precursor is investigated, and Al(OH)(3) nanosheets are in situ formed on the surface of Al1-xSix, where x = 0,10, 0,20, and 0,30 in the presence of water. The influence of the Si content, diameter of Al-Si particles, and heating parameters on the morphology and thickness of the Al(OH)(3) nanosheets is systematically explored using X-ray diffraction, electron microscopy, Fourier transform infrared spectroscopy, and N-2 adsorption/desorption isotherms. The growth mechanism of Al(OH)(3) nanosheets is revealed, and a pathway to obtain Al-Si@Al2O3 nanosheets with the desired structure and thickness is demonstrated.

卷号:12

期号:8

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