青岛科技大学  English 
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副教授 硕士生导师  

教师拼音名称:Lichengdong

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办公地点:材料科学与工程学院229房间

性别:男

联系方式:15588619659

职称:副教授

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Novel plate-stratiform nanostructured Bi12O17Cl2 with visible-light photocatalytic performance

关键字:plate-stratiform nanostructured Bi12O17Cl2; photocatalytic performance

摘要:Novel plate-stratiform nanostructured Bi12O17Cl2 was studied with its visible-light photocatalytic performance. The Bi12O17Cl2 photocatalyst synthesized by a solid-state reaction was constructed of dozens of primary nanosheets, which were stacked by a parallel array of ultrathin secondary nanosheets. The microstructure and crystal structure of Bi12O17Cl2 primary and secondary nanosheets were discovered by high-resolution transmission electron microscopy and selected-area electron diffraction analyses. Its absorption edge was determined as about 590 nm and the band gap energy was 2.1 eV. The Bi12O17Cl2 nanomaterial exhibited superior visible-light-responsive photocatalytic activity and confirmed successful photodegradation of methyl orange (MO) under visible-light irradiation. The degradation efficiency was up to 97% in 90 min. Furthermore, the Bi12O17Cl2 photocatalyst exhibited excellent photostability and high mineralization capacity for MO photodegradation reaction. The MO photodegradation process was dominated by the direct photocatalytic mechanism. The contribution from its morphology and microstructure to superior photocatalytic activity was discussed. (C) 2016 International Centre for Diffraction Data.

卷号:31

期号:1

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