李彬   

李彬,博士毕业于复旦大学化学,师从赵东元院士,博士毕业后在新加坡南洋理工大学继续博士后的研究工作。主要从事新型多孔材料的合成与应用,尤其是在微介孔材料的绿色合成、性能调控以及在催化领域中形成了独特的思想见解,取得了一系列有影响力的研究成果。(1)发展了沸石模板制备多孔缺陷碳的方法,并在氯碱工业析氯反应中表现出优异的催化性能。(2)提出了功能纳米颗粒诱导沸石从外到里重结晶的机理,为设计高效催...Detials

Cationic defects coupled with trace Pt under the assistance of corrosive engineering for efficient hydrogen electrocatalysis with large current density

Release time:2023-10-19  Hits:

  • Key Words:HYDROXIDE
  • Abstract:Exploiting efficient and durable samples toward electrocatalytic hydrogen evolution reaction (HER) with large current density is critical for commercializing hydrogen energy. Herein, Ni, Fe layered double hydroxide with cationic defects and trace Pt (Pt/D-NiFe LDH) on NiFe foam is constructed under the assistance of corrosion engineering and alkaline etching at ambient conditions. The porous nanostructure, leaf-like morphology and coexistence of defects and Pt endow the as-designed sample presents a remarkable electrocatalytic activity for HER in alkaline media with low overpotentials with 28, 163 and 217 mV to drive 10, 500 and 1000 mA cm-2. Remarkably, the catalyst enables the two-electrode electrolyzer with low voltages 1.65 and 1.72 V to attain 500 and 1000 mA cm-2. It also can be powered by solar, thermal and wind sustainable energies. The as-synthesized Pt/D-NiFe LDH has excellent catalytic activities and stability in alkaline seawater and neutral electrolytes with small overpotentials.
  • Volume:210
  • Issue:-
  • Translation or Not:no