郝春成

教授

教授 博士生导师 硕士生导师

职务:先进电工材料研究院院长

学历:博士研究生

主要任职:山东省高性能电缆料重点实验室 主任

其他任职:高压绝缘系统与先进电工材料山东省工程研究中心 主任

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Effect of Nanoporous Molecular Sieves TS-1 on Electrical Properties of Crosslinked Polyethylene Nanocomposites

发布时间:2024-12-23 点击次数:

关键字:SPACE-CHARGE; DICUMYL PEROXIDE; POLYMER; PAPER; CLAY
摘要:Crosslinked polyethylene (XLPE) is an important polyethylene modification material which is widely used in high-voltage direct current (HVDC) transmi systems. Low-density polyethylene (LDPE) was used as a matrix to improve the thermal and electrical properties of XLPE composites through the synergistic effect of a crosslinking agent and nanopore structure molecular sieve, TS-1. It was found that the electrical and thermal properties of the matrices were different due to the crosslinking degree and crosslinking efficiency, and the introduction of TS-1 enhanced the dielectric constants of the two matrices to 2.53 and 2.54, and the direct current (DC) resistivities were increased to 3 x 1012 and 4 x 1012 Omega<middle dot>m, with the enhancement of the thermal conductivity at different temperatures. As the applied voltage increases, the DC breakdown field strength is enhanced from 318 to 363 kV/mm and 330 to 356 kV/mm. The unique nanopore structure of TS-1 itself can inhibit the injection and accumulation in the internal space of crosslinked polyethylene composites, and the pore size effect of the filler can limit the development of electron impact ionization, inhibit the electron avalanche breakdown, and improve the strength of the external applied electric field (breakdown field) that TS-1/XLPE nanocomposites can withstand. This provides a new method for the preparation of nanocomposite insulating dielectric materials for HVDC transmi systems with better performance.
卷号:14
期号:11
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