青岛科技大学  English 
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教师拼音名称:HRJ

学历:博士研究生

联系方式:青岛郑州路53号(青岛科技大学材料学院)

学位:工学博士

毕业院校:山东大学

学科:

材料物理与化学

材料学

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CTAB-assisted precipitation synthesis and photoluminescence properties of olive-like YVO4:Eu nanocrystallites

关键字:Eu-doped YVO4; Surfactant-assisted precipitation method; Nanocrystallites; Photoluminescence

摘要:The olive-like YVO4:Eu nanocrystallites with the equatorial diameters ranging from 50 to 80 nm and the lengths in the range of 100-130 nm have been prepared via cetyltrimethylammonium bromide (CTAB)assisted precipitation method at room temperature in ammonia water media. The olive-like morphologies of nanocrystallites are preserved for the samples calcined at 200 and 400 degrees C, respectively, while the raisin-like nanocrystallites are obtained after the sample was calcined at 600 degrees C. The olive-like or raisin-like YVO4:Eu nanocrystallites upon excitation at 275 nm exhibit the characteristic emission bands of D-5(0)-F-7(J) (J = 1, 2, 3, 4) transitions of Eu3+, with the D-5(0)-F-7(2) transition (split into two peaks at 617 and 621 nm) being the most prominent band. The red-to-orange ratio of Eu3+ for YVO4:Eu nanocrystallites varied with the change in the calcining temperature or the Eu-doped concentration, respectively. Both the calcining temperature and Eu-doped concentration could influence the emission color purity of the YVO4:Eu nanocrystallites. (C) 2009 Elsevier B.V. All rights reserved.

卷号:32

期号:2

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崂山校区 - 山东省青岛市松岭路99号   
四方校区 - 山东省青岛市郑州路53号   
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