Key Words:Lithium-ion batteries;Anodes - Ions - Iron - Iron compounds - Lithium compounds - Phosphorus compounds

Abstract:Due to the always accompanied huge volume change during cycling, it is still a great challenge to achieve stable large-capacity anode for Li-ion battery. Herein, iron fumarate has been exploited as a novel and promising anode material, which has the inherent advantages of low cost and eco-friendliness. During charge-discharge cycling, the flexible organic fumarate ligands act as high-efficient buffer materials to accommodate the volume change of Fe-based active species. Through in-situ conductive Fe<inf>2</inf>P decorating, the bulk electronic conductivity of the iron fumarate-based anode material can be effectively improved to achieve fast electrochemical response. Consequently, the iron fumarate-based anode material shows excellent structure stability with a capacity fading as low as 0.03% per cycle after 1400 cycles at 3.0 A g⁻¹ and achieves superior rate performance with a high capacity of 520 mAh g⁻¹ at 8.0 A g⁻¹. This study suggests that iron fumarate is a potential anode material for large-scale applications.<br/> © 2019 Elsevier B.V.

Volume:809

Issue:No

Translation or Not:no