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Side-functionalized two-dimensional polymers synthesized via on-surface Schiff-base coupling

Release time:2023-10-19 Hits:

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Abstract:An imine-based 2D polymer side-functionalized with o-hydroxyl group was designed in regard to its potential ability to serve as a chelating agent and synthesized on a highly oriented pyrolytic graphite surface with a relatively low annealing temperature. When annealed to a higher temperature the o-hydroxyl group reacts further with the imine group, leading to the formation of oxazoline, which causes significant distortion to the network. The formation of oxazoline was further confirmed by ATR-FTIR.
Volume:51
Issue:41
Translation or Not:no