论文成果
Facile surfactant-assisted synthesis of CTAB-incorporated MoS<inf>2</inf>ultrathin nanosheets for efficient hydrogen evolution
- 发布时间：2021-03-15
- 点击次数：
- 关键字：Molybdenum compounds;Catalyst activity - Electrocatalysts - Nanosheets - Slope stability - Specific surface area - Surface active agents;Catalytic active sites - Cetyl trimethyl ammonium bromides - Electrical conductivity - High specific surface area - Hydrogen evolution reactions - Hydrothermal process - Surfactant assisted synthesis - Ultrathin nanosheets
- 摘要：Molybdenum disulfide (MoS<inf>2</inf>) has emerged as a promising electrocatalyst for catalyzing protons to hydrogen via the so-called hydrogen evolution reaction (HER). In order to enhance the HER activity, CTAB (cetyltrimethyl ammonium bromide)-incorporated MoS<inf>2</inf>ultrathin nanosheets with high specific surface area and more catalytic active sites have been successfully synthesized via a facile surfactant-assisted hydrothermal approach. Adding CTAB to the hydrothermal process can effectively regulate both structural and electronic benefits by controllable disorder engineering and simultaneous CTAB incorporation in MoS<inf>2</inf>catalysts, leading to a higher specific surface area, more catalytic active sites and better electrical conductivity for improving HER activity. The optimized CTAB-incorporated MoS<inf>2</inf>ultrathin nanosheets exhibit excellent activity for HER with a small onset potential of 88 mV, a low Tafel slope of 55 mV dec<sup>-1</sup>, and relatively good stability. © The Royal Society of Chemistry 2016.
- 卷号：6
- 期号：20
- 是否译文：否