Carbon encapsulated nanosheet-assembled MoS2 nanospheres with highly reversible lithium storage

Key Words:MoS2; Nanosheets; Nanospheres; Anode; Lithium ion batteries

Abstract:Carbon encapsulated nanosheet-assembled MoS2 (C@MoS2) nanospheres have been synthesized using poly(vinylpyrrolidone) (PVP) as surfactant and carbon source via hydrothermal approach in combination with high-temperature calcination process. PVP plays an important role in the formation of nanosheet-assembled MoS2 nanospheres, which can be in-situ converted into amorphous carbon to encapsulate MoS2. When evaluated for electrochemical lithium storage properties, the C@MoS2 nanospheres exhibit enhanced electrochemical energy storage performances compared to the bare MoS2 nanosheets, including high specific capacity (1135.8 mAh g(-1) at 0.1 A g(-1)), excellent rate capability (384.4 mAh g(-1) at 8 A g(-1) and 330.5 mAh g(-1) at 10 A g(-1)), and good cycling stability (97.03% capacity retention after 100 cycles at 0.5 A g(-1)). The enhanced lithium storage performances of the C@MoS2 nanospheres can be ascribed to the boosted electronic conductivity arising from PVP derived carbon, and the facilitated lithium ion transport due to the shorter diffusion length of MoS2 nanosheet-assembled structures. (C) 2016 Elsevier B.V. All rights reserved.

Volume:304

Translation or Not:no