Facile surfactant-assisted synthesis of CTAB-incorporated MoS2 ultrathin nanosheets for efficient hydrogen evolution

Release time:2021-03-15 Hits:

Key Words:HYDROTHERMAL SYNTHESIS; WS2 NANOSHEETS; ELECTROCATALYST; CATALYST; NANOPARTICLES; PERFORMANCE; GRAPHENE; EXFOLIATION; HYBRIDS

Abstract:Molybdenum disulfide (MoS2) has emerged as a promising electrocatalyst for catalyzing protons to hydrogen via the so-called hydrogen evolution reaction (HER). In order to enhance the HER activity, CTAB (cetyltrimethyl ammonium bromide)-incorporated MoS2 ultrathin nanosheets with high specific surface area and more catalytic active sites have been successfully synthesized via a facile surfactant-assisted hydrothermal approach. Adding CTAB to the hydrothermal process can effectively regulate both structural and electronic benefits by controllable disorder engineering and simultaneous CTAB incorporation in MoS2 catalysts, leading to a higher specific surface area, more catalytic active sites and better electrical conductivity for improving HER activity. The optimized CTAB-incorporated MoS2 ultrathin nanosheets exhibit excellent activity for HER with a small onset potential of 88 mV, a low Tafel slope of 55 mV dec(-1), and relatively good stability.

Volume:6

Issue:20

Translation or Not:no