青岛科技大学  English 
陈英杰
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教师拼音名称:chenyingjie

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毕业院校:中国科学院海洋研究所

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材料学

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2018-10-09 我最喜爱的老师

2019-09-13 校级优秀班主任

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N, P-codoped porous carbon derived from chitosan with hierarchical N-enriched structure and ultra-high specific surface Area toward high-performance supercapacitors

关键字:ACTIVATED CARBON; SUPERIOR PERFORMANCE; MESOPOROUS CARBON; NITROGEN; PHOSPHORUS; ELECTRODES; OXYGEN; COMPOSITES; ADSORPTION; STRATEGY

摘要:In this work, a facile "carbonization-activation" strategy is developed to synthesize N, P-codoped hierarchical porous carbon. Phosphoric acid is innovatively introduced during the hydrothermal process to achieve in-situ P doping as well as create abundant pores, and the employment of sodamide is of vital importance to simultaneously serve as activating agent and N-source to succeed a high-level N doping. Thus, the obtained samples exhibit a unique three-dimensional hierarchical structure with an ultra-high specific surface area (3646 m(2) g(-1)) and ultra-high N-doping level (9.81 at.%). Computational analyses confirm that N, P co-doping and higher N content can enhance active sites and widen potential differences of carbon materials to improve their capacitance. The as-prepared carbon materials demonstrate superior electrochemical performances, such as an ultra-high capacitance of 586 F g(-1 )at 1 A g(-1), a superior rate capability of 409 F g(-1) at 20 A g(-1), and excellent long-term stability of 97 % capacitance retention after 10,000 cycles in 6 M KOH. Moreover, an assembled symmetric supercapacitor delivers a high energy density of 28.1 Wh kg(-1) at the power density of 450 W kg(-1) in 1 M Na2SO4, demonstrating a great potential for applications in supercapacitors. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

卷号:88

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